学习与工作经历：
1994.9-1998.6 天津科技大学 食品与工程系，本科
1998.9-2000.6 湖南长沙LG曙光电子有限公司，工程师
2000.9-2003.6 南京大学化学化工学院配位化学国家重点实验室，硕士
2003.9-2007.4 香港科技大学 化学系，博士
2007.4-2010.4 香港科技大学 化学系，博士后
2010.4-2011.11 中南大学 化学化工学院，副教授
2011.12-现在 中南大学 化学化工学院，教授，化学系副主任
研究方向：
● Molecular synthetic inorganic and organometallic chemistry
● High oxidation state metal complexes
● Transition metal complexes with metal-ligand multiple bonds
Our research is focused on investigation of new reactions and development
of innovative synthetic and characterization methodologies (particularly in
structural chemistry). The research interests are in the field of synthetic
inorganic and organometallic chemistry, current research projects include:
Synthesis and reactivity of the metal-nitrogen multiple bonds in
the high oxidation-state ruthenium complexes
We synthesized and characterized a series of ruthenium complexes with
ruthenium-nitrogen multiple bond containing an oxygen tripodal ligand, and
explored steric effect and electronic effect of substituents of ligands for
the stability and reactivity of these complexes, and studied the reactivity
of ruthenium-nitrogen multiple bonds with organic substrates. We reported
the formation of dinuclear imido complex from the reaction of a
ruthenium(VI) nitride with a ruthenium(II) hydride.
Synthesis and reactivity of the M(IV) (M = Ti, Zr, Ce) complexes
with oxygen donor ligand
a. Aqueous chemistry of M(IV) (M = Ti, Zr, Ce) complexes
We reported the synthesis of M(IV) (M = Ti, Zr, Ce) complexes with chelating
oxygen ligands that may serve as models for metal aqua ions and metal oxide
surfaces. Ti(IV) and Zr(IV) triflato and sulfato compounds are synthesized.
Hydrolysis of these triflato compounds in aqua media leads to mono-, di-,
tri- or tetranuclear group 4 oxo and hydroxo compounds. The interconversion
between these polynuclear Zr(IV) compounds are directed by pH value.
b. metal-oxo anions as catalyst activated by Lewis-acid
M=O group in meta oxo anions MOxy- is activated by high oxidation state
metal compounds LnM’ due to LnM’ as a lewis acid coordination with metal
oxo anions to form LnM’-O-M=O. Some novel structures of these compounds
are characterized by single crystal X-ray diffraction. The activated MOxy-
can catalytically undergo oxo transfer to the sulfide and alkane at room
temperature.
High-oxidation state Rh and Ir organometallic complexes and C-H
bond activation
We synthesized a series of Rh and Ir complexes [M(dtbpy)(R)]. Heating
condition results in intramolecular C-H activation of the neophyl ligand,
and cationic Ir and Rh alkyl complexes containing the non-coordinating
counteranion are capable of catalyzing the H/D exchange of THF using
D2O as the deuterium source.
Ruthenium phosphonate complexes and their magnetic properties
Ruthenium phosphonate compounds with a mixed valent diruthenium paddlewheel
core are synthesized. Template and pH value directed assembly of diruthenium
diphosphonates with different topologies and oxidation states. Magnetic
properties of diruthenium compounds are studied.
参加学术会议：
9. 中国化学会第28届学术年会，成都（2012）
8. 中国化学会第八届全国无机化学会议，哈尔滨（2011）
7. 第四届全国多酸化学学术研讨会，通辽（口头报告，2011）
6. 11th Conference on Solid State Chemistry and Inorganic Synthesis joint
with 2nd Dalton Trans. International Symposium, Shanghai (oral, 2010)
5. 2nd Asian Coordination Chemistry Conference, Nanjing (poster, 2009)
4. 6th National Conference on Coordination Chemistry (& International
Symposium on Coordination Chemistry), Hong Kong (poster, 2009)
3. 37th International Conference on Coordination Chemistry, South Africa
(poster, 2006)
2. International Symposium on Catalysis and Fine Chemicals 2004 (C & FC
2004), Hong Kong (poster, 2004)
1. The Sixth Conference of the Asian Crystallographic Association, Hong Kong
(poster, 2004)
